2018 Research in the Capitol
Silylation of Pyridine and Pyridine Derivatives using Diruthenium Catalysts [Poster]
Presentation Type
Poster Presentation (Electronic Copy Not Available)
Keywords
Silylation; Pyridine; Pyridine--Derivaties;
Abstract
Silylation of C-H bonds in pyridine can provide a building block that can be then used for further reactions. The reaction between pyridine and various silanes utilizes a diruthenium complex as a catalyst. This reaction is carried out at 160-180 °C with different diruthenium complexes with 3- silylpyridine as the main product (30-40% yield). The different effects of each diruthenium compound on the reaction will be presented. Reactions have also been done using pyridine derivatives and the percent yields and possible intermediates will be presented. The reaction products were isolated and fully characterized by NMR spectroscopy and GC-MS.
Start Date
3-4-2018 11:30 AM
End Date
3-4-2018 1:30 PM
Event Host
University Honors Programs, Iowa Regent Universities
Faculty Advisor
Martin Chin
Department
Department of Chemistry and Biochemistry
Department
McNair Scholars Program at UNI
Copyright
©2018 Josh Prybil
File Format
application/pdf
Recommended Citation
Prybil, Josh Wesley, "Silylation of Pyridine and Pyridine Derivatives using Diruthenium Catalysts [Poster]" (2018). Research in the Capitol. 15.
https://scholarworks.uni.edu/rcapitol/2018/all/15
Silylation of Pyridine and Pyridine Derivatives using Diruthenium Catalysts [Poster]
Silylation of C-H bonds in pyridine can provide a building block that can be then used for further reactions. The reaction between pyridine and various silanes utilizes a diruthenium complex as a catalyst. This reaction is carried out at 160-180 °C with different diruthenium complexes with 3- silylpyridine as the main product (30-40% yield). The different effects of each diruthenium compound on the reaction will be presented. Reactions have also been done using pyridine derivatives and the percent yields and possible intermediates will be presented. The reaction products were isolated and fully characterized by NMR spectroscopy and GC-MS.
