Dissertations and Theses @ UNI
Availability
Open Access Thesis
Keywords
Phenylenediamine; Chromium; Complex compounds;
Abstract
Chromium(III) complexes of o-phenylenediamine were prepared by mixing hot 1-butanol solutions of transtetraaquadichlorochromium(III) chloride 2-hydrate and o-phenylenediamine. From the elemental analyses of four preparations, the empirical formula was determined to be CrCl3C12H18N4O1.7. It was found, by the analysis of infrared spectra, that o-phenylenediamine acted as bidentate ligands and, by chloride analysis, that each molecule of the complex contained one free chloride ion. The following formula was proposed: [CrCl2(C6H8N2)2]Cl·xH2O.
Year of Submission
1972
Degree Name
Master of Arts
Department
Department of Chemistry
First Advisor
James C. Chang
Second Advisor
Paul E. Rider
Third Advisor
Carl Wehner
Date Original
1973
Object Description
1 PDF file (52 leaves)
Copyright
©1972 Barbara J. Kacena
Language
en
File Format
application/pdf
Recommended Citation
Kacena, Barbara J., "A Study of Chromium (III) Complexes of o-Phenylenediamine" (1972). Dissertations and Theses @ UNI. 3104.
https://scholarworks.uni.edu/etd/3104
Comments
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