The use of 2-Chlorophenoxyacetyl Chloride in the Preparation of Mixed Diacyl Derivatives of Ortho Aminophenols

Authors

Paul H. Bacher, State University of Iowa
L. Chas. Raiford, State University of IowaFollow

Document Type

Research

Abstract

Raiford and coworkers (1) have proved by a long series of experiments that when two acyl radicals, R-Ć=O and R'-Ć =O, are introduced into an ortho aminophenol only one mixed diacyl derivative can generally be obtained, regardless of the order of introduction of the radicals; and in this product the heavier and more acidic of these groups is usually found attached to nitrogen. To meet this requirement the migration of acyl from nitrogen to oxygen must occur in one of these reactions. If the acyls are R-Ć=O and R-0-Ć=O the latter is most frequently found on nitrogen.

Publication Date

1943

Journal Title

Proceedings of the Iowa Academy of Science

Volume

50

Issue

1

First Page

247

Last Page

251

Copyright

©1943 Iowa Academy of Science, Inc.

Language

en

File Format

application/pdf

Recommended Citation

Bacher, Paul H. and Raiford, L. Chas. (1943) "The use of 2-Chlorophenoxyacetyl Chloride in the Preparation of Mixed Diacyl Derivatives of Ortho Aminophenols," Proceedings of the Iowa Academy of Science, 50(1), 247-251.
Available at: https://scholarworks.uni.edu/pias/vol50/iss1/20