•  
  •  
 

Document Type

Research

Abstract

Measurements have been made upon the hydrolysis rates of ketimine hydrochlorides to obtain information concerning the relation between their varied structures and stability toward hydrolysis1. The hydrogen ion concentration might appear as a catalytic factor in this hydrolysis2. It would thus seem necessary to determine these hydrolysis rates at the same hydrogen ion concentration if this factor has a marked effect. Different ketimine hydrochlorides alone in water produce, in the dilute solutions usually employed, pH values ranging initially from about a.6 to 5.3 and increasing in each case toward the pH of the equivalent ammonium chloride formed as the result of hydrolysis. Certain measurements on the hydrolysis rates of ketimine hydrochlorides of widely different initial pH values in water, to which an equivalent of hydrochloric acid was added, showed that their speed was actually lowered by this hydrogen ion increase although not enough to affect the general order of the rate.

Publication Date

1941

Journal Title

Proceedings of the Iowa Academy of Science

Volume

48

Issue

1

First Page

247

Last Page

248

Copyright

©1941 Iowa Academy of Science, Inc.

Language

en

File Format

application/pdf

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.