Cyanogen Chloride with Organomagnesium Compounds

Authors

George H. Coleman, State University of IowaFollow
Robert W. Leeper, State University of IowaFollow

Document Type

Research

Abstract

A Grignard reagent is commonly represented by the formula RMgX. It has been established, however, that the following equilibrium exists in such a reagent (1, 2, 3). 2RMgXR₂Mg + MgX₂. The assumption has been made that almost without exception the reactions of RMgX and R2Mg are the same and that therefore the representation of the reagent as RMgX is permissible. One of the first exceptions noted was in the reaction between alkyl sulfonates and the Grignard reagent (4, 5, 6). In this work it was shown that each component in the above equilibrium has a different effect in the reaction.

Publication Date

1940

Journal Title

Proceedings of the Iowa Academy of Science

Volume

47

Issue

1

First Page

201

Last Page

205

Copyright

©1940 Iowa Academy of Science, Inc.

Language

en

File Format

application/pdf

Recommended Citation

Coleman, George H. and Leeper, Robert W. (1940) "Cyanogen Chloride with Organomagnesium Compounds," Proceedings of the Iowa Academy of Science, 47(1), 201-205.
Available at: https://scholarworks.uni.edu/pias/vol47/iss1/39