Home > Iowa Academy of Science > Journals & Newsletters > Proceedings of the Iowa Academy of Science > Volume 43 (1936) > Annual Issue
Document Type
Research
Abstract
The yields of primary amines from monochloroamine and Grignard reagents prepared from alkyl halides vary greatly with the halogen present in the reagent. For example the yields from n-butyl reagents decrease from an average of 60 per cent with the chloride to about 15 per cent or less with the iodide. The percentage of dialkylmagnesium present in the three n-butyl reagents is about the same being above 65 per cent in each. With di-nbutylmagnesium however prepared from each of the three n-butyl Grignard reagents by the dioxane method the yields of n-butylamine are above 80 per cent.
Publication Date
1936
Journal Title
Proceedings of the Iowa Academy of Science
Volume
43
Issue
1
First Page
201
Last Page
201
Copyright
©1936 Iowa Academy of Science, Inc.
Language
en
File Format
application/pdf
Recommended Citation
Coleman, George H. and Blomquist, Richard F.
(1936)
"The Reaction of Dialkylmagnesium with Monochloroamine,"
Proceedings of the Iowa Academy of Science, 43(1), 201-201.
Available at:
https://scholarworks.uni.edu/pias/vol43/iss1/43