Ozone had no effect on diphenylethyleneimine. The benzoyl derivative was prepared in pyridine by the action of benzoyl chloride. In dilute sodium hydroxide the same reagent formed α-β-diphenyl-β-chloroethylamine. This compound was changed to benzoyl diphenylethyleneimine by heating with alcoholic sodium ethylate. On being heated to 225° diphenylethyleneimine rearranged to benzalbenzylamine. A number of experiments were tried in an attempt to prepare aminoethenes but the results were not conclusive.
Proceedings of the Iowa Academy of Science
© Copyright 1933 by the Iowa Academy of Science, Inc.
Coleman, George H. and Waugh, G. P.
"Some Reactions of Diphenyletyleneimine and Attempts to Prepare Aminoethenes,"
Proceedings of the Iowa Academy of Science, 40(1), 115-115.
Available at: https://scholarworks.uni.edu/pias/vol40/iss1/57