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Document Type

Research

Abstract

Diphenylketene reacts with nitrogen trichloride in carbon tetrachloride solution. When this solution is warmed to 50° C with sodium hydroxide the addition product undergoes a rearrangement with the formation of imidobenzophenone. This rearrangement is similar to the rearrangement in Hofmann's method for the preparation of primary amines from amides. On passing dry HCl into the carbon tetrachloride solution, the hydrochloride of this compound is precipitated.

Publication Date

1927

Journal Title

Proceedings of the Iowa Academy of Science

Volume

34

Issue

1

First Page

223

Last Page

223

Copyright

© Copyright 1927 by the Iowa Academy of Science, Inc.

Language

EN

File Format

application/pdf

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