Home > Iowa Academy of Science > Journals & Newsletters > Proceedings of the Iowa Academy of Science > Volume 34 (1927) > Annual Issue
Document Type
Research
Abstract
Diphenylketene reacts with nitrogen trichloride in carbon tetrachloride solution. When this solution is warmed to 50° C with sodium hydroxide the addition product undergoes a rearrangement with the formation of imidobenzophenone. This rearrangement is similar to the rearrangement in Hofmann's method for the preparation of primary amines from amides. On passing dry HCl into the carbon tetrachloride solution, the hydrochloride of this compound is precipitated.
Publication Date
1927
Journal Title
Proceedings of the Iowa Academy of Science
Volume
34
Issue
1
First Page
223
Last Page
223
Copyright
©1927 Iowa Academy of Science, Inc.
Language
en
File Format
application/pdf
Recommended Citation
Coleman, G. H. and Campbell, A. W.
(1927)
"Diphenylketene with Nitrogen Trichloride,"
Proceedings of the Iowa Academy of Science, 34(1), 223-223.
Available at:
https://scholarworks.uni.edu/pias/vol34/iss1/54