Home > Iowa Academy of Science > Journals & Newsletters > Proceedings of the Iowa Academy of Science > Volume 32 (1925) > Annual Issue
Document Type
Research
Abstract
A study of the velocity factors involved in the preparation of octane by the Wurtz reaction has been made and a new technic developed. Using 50 grams of butyl bromide, 10.5 grams of bird shot sodium or a 25% excess, and 40 cc. of ether, at the reflux temperature, yields of 73% have been obtained in five hours when the mixture is agitated, and without agitation, but 44%. By dropping the butyl bromide on the sodium contained in a pyrex round bottomed flask, high yields were obtained with times of reaction less than an hour. The product obtained is high grade. This reaction can be carried out in the absence of a solvent thus eliminating one step in the process, namely the separation from the solvent. As the sodium is used up fresh charges can be introduced and the process kept up.
Publication Date
1925
Journal Title
Proceedings of the Iowa Academy of Science
Volume
32
Issue
1
First Page
327
Last Page
328
Copyright
©1925 Iowa Academy of Science, Inc.
Language
en
File Format
application/pdf
Recommended Citation
Lewis, H. F. and Yohe, G. Roert
(1925)
"The Preparation of Pure Octane,"
Proceedings of the Iowa Academy of Science, 32(1), 327-328.
Available at:
https://scholarworks.uni.edu/pias/vol32/iss1/53