Synthesis And Characterization Of A Zirconium Complex Containing A Corannulene-Based Ligand

Authors

Robert M. Chin, University of Northern IowaFollow
Michael S. Jarosh, University of Northern IowaFollow
Jason D. Russell, University of Northern Iowa
Rene J. Lachicotte, University of Rochester

Document Type

Article

Journal/Book/Conference Title

Organometallics

Volume

21

Issue

10

First Page

2027

Last Page

2029

Abstract

The synthesis and characterization of a zirconium complex, containing a partially hydrogenated corannulene-based ligand was discussed. The zirconium atom was determined to be bound to the exo face of the bowl-shaped ligand. Corannulene was also found to undergo a bowl-to-bowl inversion process, and its inversion barriers were determined.

Department

Department of Chemistry

Original Publication Date

5-13-2002

DOI of published version

10.1021/om0201765

Recommended Citation

Chin, Robert M.; Jarosh, Michael S.; Russell, Jason D.; and Lachicotte, Rene J., "Synthesis And Characterization Of A Zirconium Complex Containing A Corannulene-Based Ligand" (2002). Faculty Publications. 3397.
https://scholarworks.uni.edu/facpub/3397