Faculty Publications

Title

Synthesis and characterization of a zirconium complex containing a corannulene-based ligand

Document Type

Article

Journal/Book/Conference Title

Organometallics

Volume

21

Issue

10

First Page

2027

Last Page

2029

Abstract

The synthesis and characterization of a zirconium complex, containing a partially hydrogenated corannulene-based ligand was discussed. The zirconium atom was determined to be bound to the exo face of the bowl-shaped ligand. Corannulene was also found to undergo a bowl-to-bowl inversion process, and its inversion barriers were determined.

Original Publication Date

5-13-2002

DOI of published version

10.1021/om0201765

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