"Titan Aerosol Analog Absorption Features Produced From Aromatics In Th" by Joshua A. Sebree, Melissa G. Trainer et al.
 

Faculty Publications

Titan Aerosol Analog Absorption Features Produced From Aromatics In The Far Infrared

Document Type

Article

Keywords

Atmospheres, chemistry, Spectroscopy, Titan, atmosphere

Journal/Book/Conference Title

Icarus

Volume

236

First Page

146

Last Page

152

Abstract

We present results on the formation of Titan aerosol analogs produced via far-UV irradiation of five aromatic precursors: benzene, naphthalene, pyridine, quinoline and isoquinoline. This is the first reported evidence of far-IR emission features observed below 200cm-1 in laboratory-created Titan aerosols. These laboratory studies were motivated by recent analyses of Cassini Composite Infrared Spectrometer (CIRS) spectra that show a broad aerosol emission feature in the far-IR spectral region centered near 140cm-1, which is unique to Titan's photochemically-produced aerosol (Anderson, C.M., Samuelson, R.E. [2011]. Icarus 212, 762-778). We find that all three of the aerosol analogs formed from nitrogen-containing aromatics have similar broad emission features near that of the observed CIRS far-IR aerosol spectral feature. In addition, the inclusion of 1.5% methane to that of trace amounts of benzene also gives rise to an aerosol with a weak far-IR emission feature located below 200cm-1. © 2014 Elsevier Inc.

Department

Department of Chemistry and Biochemistry

Original Publication Date

7-1-2014

DOI of published version

10.1016/j.icarus.2014.03.039

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