The reactions of some pentaammine(o-substituted benzoato)chromium(III) cations in perchloric acid and water
The reactions of pentaammine(o-fluorobenzoato)-, pentaammine(o-bromo-benzoato)- and pentaammine(o-nitrobenzoato)chromium(III) cations in 0.01 M perchloric acid solution and water have been studied at 21dgC. It was found that the reaction in acid was the release of ammonia but in water it was aquation to the pentaammineaquachromium(III) cation. The aquation rates in water decrease in the order o-fluorobenzoate, o-bromobenzoate and o-nitrobenzoate complexes, suggesting an associative mechanism. © 1987.
Original Publication Date
DOI of published version
Williamson, Rodney L. and Chang, James C., "The reactions of some pentaammine(o-substituted benzoato)chromium(III) cations in perchloric acid and water" (1987). Faculty Publications. 4723.