Faculty Publications

Title

Dopant enhanced etching of TiSe2 by scanning tunneling microscopy

Document Type

Article

Journal/Book/Conference Title

Langmuir

Volume

26

Issue

13

First Page

10980

Last Page

10984

Abstract

The surfaces of pure and Mn doped TiSe2 were etched using a scanning tunneling microscope. Both types of samples were found to etch easily when scanning was performed in ambient conditions. This process was enhanced at step edges or other surface defects. In pure samples, material was removed in a layer-by-layer fashion with a strong dependence on the scanning direction of the tip. Doped samples etched far more rapidly, to the point that stable scanning conditions were difficult to establish. Doped samples also showed a greater number of pits and other defects on their surface. A relatively small percentage of dopants was necessary to strongly impact the surface topography and stability. These results show that impurities can play a dominant role when using scanning tunneling microscopy to create surface nanostructures. © 2010 American Chemical Society.

Original Publication Date

7-6-2010

DOI of published version

10.1021/la1015803

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