The reaction of di-n-butylcadmium with either capryl chloride or benzoyl chloride at -10° in the presence of ferric chloride yields 50% of the expected ketone. The reactions of the same acid chlorides with diphenylcadmium are hampered by coupling of the aromatic cadmium reagent in the presence of the ferric chloride. A yield of 20-30% of ketone can be obtained, however, if the ferric chloride is added to the precooled acid chloride followed by the addition of the diphenylcadmium.
Proceedings of the Iowa Academy of Science
© Copyright 1963 by the Iowa Academy of Science, Inc.
Bogan, Richard; Plamondon, Joseph; and Kraus, Kenneth W.
"The Effect of Ferric Chloride on the Cadmium Reaction,"
Proceedings of the Iowa Academy of Science: Vol. 70:
, Article 35.
Available at: https://scholarworks.uni.edu/pias/vol70/iss1/35