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Document Type

Research

Abstract

Stieglitz1 pointed out in 1908 that the derivation of the solubility product law based on the application of the law of mass action to strong electrolytes is objectionable. Nevertheless many elementary textbooks still give it. Washburn2 later gave a satisfactory thermodynamic derivation, and Butler3 has more recently given a satisfactory statistical one. Another thermodynamic derivation is possible using the now familiar concepts of free energy and activity.

Publication Date

1927

Journal Title

Proceedings of the Iowa Academy of Science

Volume

34

Issue

1

First Page

213

Last Page

224

Copyright

© Copyright 1927 by the Iowa Academy of Science, Inc.

Language

EN

File Format

application/pdf

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